The latest MLP:FiM DVD will be out on June 7th. The theme this time is "Friends and Family." Here is the episodes list:

- One Bad Apple (11/24/2012)
- Maud Pie (3/15/2014)
- Hearthbreakers (10/24/2015)
- Brotherhooves Social (10/3/2015)
- Flutter Brutter (6/4/2016)

I know the movies were released shortly after their TV debut, but I don't remember an individual episode being available so soon.